Magnetic properties and magnetocaloric effect of Ce2GdCo11B4 boride


Kervan N., Kervan S., Sözeri H., GENÇER A.

Materials Chemistry and Physics, vol.116, no.2-3, pp.586-588, 2009 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 116 Issue: 2-3
  • Publication Date: 2009
  • Doi Number: 10.1016/j.matchemphys.2009.04.041
  • Journal Name: Materials Chemistry and Physics
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.586-588
  • Keywords: Magnetic materials, Magnetic properties, Magnetocaloric effect
  • Ankara Haci Bayram Veli University Affiliated: No

Abstract

Magnetic properties and magnetocaloric effects of Ce2GdCo11B4 compound were studied by means of X-ray diffraction and magnetization measurements. The sample was prepared by arc-melting. The compound crystallizes in a hexagonal Ce3Co11B4-type structure with P6/mmm space group. Ce2GdCo11B4 compound orders ferrimagnetically at TC = 301 K. A compensation point at Tcomp. = 40 K was found. The maximum magnetic entropy change |ΔSmax| of Ce2GdCo11B4 is 0.306 J kg-1 K-1 for a field change of 0-5 T. The Arrott plots show that magnetic phase transition at the Curie temperature is second-order. © 2009 Elsevier B.V. All rights reserved.