Half-Metallic Properties of the CrZrZ (Z = In, Sn, Sb, and Te) Half-Heusler Compounds by Ab Initio Calculations

Kervan S., Kervan N.

Journal of Superconductivity and Novel Magnetism, vol.30, no.3, pp.657-664, 2017 (SCI-Expanded, Scopus) identifier

  • Publication Type: Article / Article
  • Volume: 30 Issue: 3
  • Publication Date: 2017
  • Doi Number: 10.1007/s10948-016-3857-8
  • Journal Name: Journal of Superconductivity and Novel Magnetism
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.657-664
  • Keywords: DFT, Electronic structure, Half-metallic materials, Magnetic properties, Spintronics
  • Ankara Haci Bayram Veli University Affiliated: No

Abstract

Ab initio calculations based on the density functional theory (DFT) have been employed to explore the half-metallicity and magnetic properties of the CrZrZ (Z = In, Sn, Sb, and Te) half-Heusler compounds. All the CrZrZ (Z = In, Sn, Sb, and Te) half-Heusler compounds are predicted to have a half-metallic character. The CrZrZ (Z = In, Sn, Sb, and Te) half-Heusler compounds have total magnetic moments of 5.0, 4.0, 3.0, and 2.0 µ B/formula unit (f.u.), respectively, which agrees with the Slater–Pauling rule mtot = ztot − 18. The value of the magnetic moment of CrZrIn compound is expected to reach as high as 5 µ B/f.u. All the CrZrZ materials have an energy gap in the spin-up channel of 1.02, 1.23, 1.35, and 0.71 eV for Z = In, Sn, Sb, and Te, respectively, and keep half-metallicity within the wide range of lattice constants. The Curie temperatures of the CrZrZ (Z = In, Sn, Sb, and Te) compounds are estimated to be 1770, 1481, 835, and 1020 K, respectively, using the mean field approximation (MFA).