Adsorption of surfactant by hydrophobically modified Poly[2-(diethylamino) ethylmethacrylate-co-N-vinyl-2-pyrrolidone/octadecyl acrylate] hydrogels and effect of surfactant adsorption on the volume phase transition

Caykara T., Izol D., Birlik G., AKAOĞLU B.

Journal of Applied Polymer Science, vol.103, no.6, pp.3771-3775, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 103 Issue: 6
  • Publication Date: 2007
  • Doi Number: 10.1002/app.25484
  • Journal Name: Journal of Applied Polymer Science
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.3771-3775
  • Keywords: poly[2-(diethylamino)ethylmethacrylate-co-N-vinyl-2-pyrrolid, one/ octadecyl acrylate), hydrophobically modified hydrogels, surfactant, adsorption
  • Ankara Haci Bayram Veli University Affiliated: No


Hydrophobically modified poly[2-(diethylamino)ethylmethacrylate-co-N-vinyl- 2-pyrrolidone/octadecyl acrylate) [P(DEAEMA-co-NVP/OA)] hydrogels were synthesized by free-radical crosslinking copolymerization of 2-(diethylamino)ethylmethacrylate (DEAEMA), N-vinyl-2pyrrolidone (NVP) with different amounts of hydrophobic comonomer octadecyl acrylate (OA) in ferf-butanol with ethylene glycole dimethacrylate (EGDMA) as a crosslinker. The swelling equilibrium of the hydrogels was investigated as a function of temperature and hydrophobic comonomer content in aqueous solutions of the anionic surfactant sodium dodecyl sulfate (SDS) and the cationic surfactant dodecyltrimethylammonium bromide (DTAB). The results indicated that the swelling behavior and temperature sensitivity of the hydrogels were affected by the type and concentration of surfactant solutions. Additionally, the amount of the adsorbed SDS and DTAB molecules onto the hydrogels was determined by fluorescence measurements. An increase of OA content in the hydrogel caused an increase in the amount of adsorbed surfactant mole cules in both media. © 2006 Wiley Periodicals, Inc.