Robust and flexible superhydrophobic/superoleophilic melamine sponges for oil-water separation


DEMİREL G., Aygül E.

Colloids and Surfaces A: Physicochemical and Engineering Aspects, cilt.577, ss.613-621, 2019 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 577
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.colsurfa.2019.05.081
  • Dergi Adı: Colloids and Surfaces A: Physicochemical and Engineering Aspects
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.613-621
  • Anahtar Kelimeler: Melamine sponge, Superhydrophobic, Superoleophilic, Oil/water separation, Separator, ORGANIC-SOLVENT, FABRICATION, ABSORPTION, SURFACES, REMOVAL, POLYMER, SILANE, FOAM
  • Ankara Hacı Bayram Veli Üniversitesi Adresli: Evet

Özet

© 2019 Elsevier B.V.In this study, we have demonstrated a facile and cost-eff ;ective method to fabricate superhydrophobic/superoleophilic melamine sponges for oil/water separation. The superhydrophobic/superoleophilic sponges (S-MSs) were fabricated by using a three-step process including GPTS/APTES modification, SiO2 NPs binding, and OTS modification. The modifications of melamine sponges were confirmed by XPS and SEM characterization. The S-MSs showed excellent sorption capacities for various oils and organic solvents. More importantly, the S-MSs exhibited an excellent separation efficiency which was greater than 97% after even 25 cycles. In addition, the S-MSs exhibited excellent mechanical and chemical durability against harsh environmental conditions such as different chemicals, different temperatures, tape-test, and UV exposure. Moreover, the S-MSs are able to maintain the repellency against strong acid and alkali droplets. The combination of these excellent mechanical properties and the selectivity against oils have made the S-MSs strong candidate for a range of industrial applications.