Quantum - chemical investigation on the addition of chlorine to homobenzobarrelene
Modelling, Measurement and Control C, cilt.61, sa.3-4, ss.11-19, 2000 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 61 Sayı: 3-4
- Basım Tarihi: 2000
- Dergi Adı: Modelling, Measurement and Control C
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.11-19
- Ankara Hacı Bayram Veli Üniversitesi Adresli: Hayır
Özet
In the electrophilic addition of chlorine to homobenzobarrelene (HBB), the HBB-Cl 2 molecular complexes have been investigated by AM1 semiempirical method and HBB-Cl 2 (endo) molecular complex has been found to be more stable than exo-complex. The cationic intermediates of the electrophilic addition have been searched by MNDO method. A benzylic type rearranged cation has been found as the most stable one among the cationic intermediates. Furthermore, the radicalic intermediates in the radicalic addition of chlorine to HBB have also been investigated and endo-chloro radical has been found to be more stable than exo-radicalic intermediate.